Materials Science Heals

Whenever I see the term ‘self-healing’ my bullshit meter immediately alarms, however Nissan has produced a self-healing iPhone case with some awesome materials science to back it up. The case is expected to be distributed later this year, so I haven’t gotten my wanting (and clumsy) hands on one myself. To me this is a ‘when I see it, I will believe it’ situation, but the science is intriguing.

Nissan originally invested in the development to form a self-healing car paint, however now they have transformed it into an iPhone case. The self-healing car paint is already on several current Nissan models including the Murano, 370Z, and the X-Trail. The caveat is its limitations to heal only ‘fine’ scratches.

The case consists of polyrotaxane. The name rotaxane derives from the Latin name rota (wheel) and axis (axel). Rotaxane is a chemical compound looks like a dumbbell with a macrocyclic ring trapped between the two ends. Polyrotaxane, the polymeric form, is a dumbbell with many rings around it.

In the scientific literature, there are many chemical variations in the blue dumbbell structure and in the green macrocyclic ring. The diversity in chemical structure probably results in various applications of this class of compounds. Mechanistic details were scarce, but it is a class of compounds I plan to keep my eye on.


Jacqueline, a true Floridian, wandered up to the tundra of Athens, Georgia to receive her PhD in computational quantum chemistry. Returning to her roots, she is currently working as a postdoctoral researcher in Tampa in the field of computational biochemistry investigating the wonders of penicillin-like drugs. When she is not slaving over the computer, her varied interests include international travel, Brazilian jiu jitsu, kickboxing, fancy food, (American) football, and Belgian quadrupels. She is also the founder of, a football blog with an exclusive female writing staff. Check out her sports ramblings there or follow her on Twitter @jhargis9.

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  1. Bout time we had a physical science & engineering post up in here. We need more of these posts! Thanks for this.

    I wonder how expensive this material is in general and whether it will make sense to move it into manufacturing. I’ve built lots of prototypes in my life which were totally infeasible to produce on a large scale.

    1. There’s not much point in a condom healing *after* it’s burst..

      But yours was the natural question to ask XD

      1. Consider this: earlier damage could heal, including any flaw that may cause an eventual burst.

        I imagine the packaging would have to be modified to prevent the item healing into a closed state.

        OTOH the device could potentially adjust itself to the size and shape of your unit for a perfect fit! It could even fit itself – look no hands!

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